In the petroleum industry, separators play an extremely crucial role. Their core mission is to efficiently separate the different phases of substances in crude oil, such as oil, water, and gas, to facilitate subsequent processing and refining. However, the efficiency of separators is not fixed but is influenced by a variety of complex factors. These factors interact with each other, collectively determining whether the separator can complete its task efficiently. This paper will delve into the many factors that affect separator efficiency and offer practical optimization suggestions to provide a reference for the efficient operation of separators in the petroleum industry.
Particle size distribution is one of the most critical factors influencing separator efficiency. While this distribution varies by incoming medium, it typically follows a normal distribution curve. It can be categorized into three typical cases:
Below Critical Diameter: When most particles are smaller than the separator's critical diameter, fine particles dominate. According to Stokes' Law, a droplet's terminal settling velocity is proportional to the square of its diameter. Thus, smaller particles settle more slowly, resulting in lower separation efficiency. For example, crude oil with a high content of fine oil droplets poses challenges in separating oil from water effectively.
Around Critical Diameter: When particle sizes are near the separator's critical diameter, most can be fully separated. This is the ideal operating condition and the basis for most separator designs. Controlling the feed to match this distribution enables peak separation performance.
Above Critical Diameter: Larger particles are more easily separated, but this often indicates an oversized separator, leading to inefficient resource use—similar to using an oversized sieve to separate large grains of sand.
Theoretically, droplets with diameters equal to or larger than the critical diameter can be completely separated. The smaller the critical diameter, the higher the efficiency. However, the critical diameter is influenced by factors such as continuous-phase viscosity, horizontal velocity, flow path geometry, and density differences between the dispersed and continuous phases. Any change in these parameters affects the critical diameter and, consequently, separator performance.
Crude oil extracted from oil wells contains a large amount of gas. If these gases are not properly treated, they can have a serious negative impact on the operation of the separator. On the one hand, gases disrupt the flow field inside the equipment, making the trajectories of droplets complex and difficult to separate according to the normal design. On the other hand, gases occupy space within the equipment, reducing the effective space for oil-water separation and lowering the equipment efficiency.
To address this issue, it is recommended that crude oil be pre-treated for gas removal before entering the separator. This can be done through gas separation devices to separate most of the gas or by using gas compression technology to reduce the volume of gas, thereby minimizing interference with the separator's operation. Additionally, during equipment design and operation, gas guidance devices can be added to facilitate the smooth discharge of gas, reducing its residence time within the equipment and further enhancing the efficiency of the separator.
Chemical injection is a commonly used optimization method in the operation of separators. However, traditional injection methods have issues such as uneven distribution of chemicals, which can affect separation efficiency. To this end, it is suggested to adopt a phase-separated injection method, that is, to inject water-soluble chemicals below the interface layer and oil-soluble chemicals above the interface layer, with separate treatment of the interface layer. Selecting chemical demulsifiers that can form a temporary transition layer can enable the chemicals to work more effectively and improve the oil-water separation effect.
For example, when processing crude oil containing a large amount of emulsified oil, injecting water-soluble demulsifiers below the interface layer can break down the emulsified oil structure, making it easier to separate from water. Injecting oil-soluble demulsifiers above the interface layer can promote the coalescence of oil droplets and improve oil separation efficiency. Separate treatment of the interface layer can control the position of the oil-water interface, reduce emulsification, and optimize the separation effect.
Interface sludge is a common problem in the operation of separators, with complex components including paraffin, solid particles, and undecomposed emulsions. Different treatment methods should be adopted according to the specific components.
For most interface sludge, it can be decomposed by increasing the process temperature. Intermittent heating methods are commonly used, which can be completed manually or automatically. Heating is particularly effective for melting paraffin sludge and undecomposed emulsified sludge. When the temperature is above the initial melting point of paraffin, the sludge will melt. For stable solid particle sludge, wetting agents can be used to make it wet and settle in water, which can then be washed away with water. Demulsifiers can be used to treat undecomposed interface emulsions. Chemical treatment is a universal method for dissolving interface sludge, and external discharge devices can be used to remove the sludge from the process for further treatment.
However, sludge containing asphaltene and chemically stabilized sludge is more difficult to treat. These types of sludge are the most difficult to dissolve, and the only treatment method is to dilute them by mixing. In actual operations, it is necessary to choose the appropriate treatment method based on the specific components and properties of the sludge to ensure the normal operation of the equipment and avoid equipment blockage or reduced separation efficiency due to sludge accumulation.
The separation efficiency equation shows a direct relationship with droplet diameter squared and an inverse relationship with flow path height. Thus, two structural innovations can significantly enhance separator performance:
Using multiple internal plates divides the separator's main flow path into smaller sub-channels. This reduces turbulence, extends droplet residence time, and increases opportunities for droplet-wall collisions, encouraging coalescence and improving overall efficiency.
This technique increases droplet size using:
Coalescing Media: Surfaces that facilitate droplet collision and coalescence.
Electric Fields: Electrically induced droplet movement increases collision probability.
Chemical Demulsifiers: Break emulsions to promote droplet growth.
These measures create size disparities among droplets, enhancing gravitational separation and increasing total efficiency.
Generally speaking, the longer the residence time, the better the separation effect, as droplets have more time to settle and coalesce within the separator. However, extending the residence time will increase the equipment size, adding to manufacturing costs and space requirements. Therefore, the selection of residence time needs to be considered comprehensively, with the goal of achieving the shortest residence time possible while meeting separation requirements.
In actual production, factors such as water washing and turbulence can cause the measured residence time to be slightly longer than the actual residence time in the equipment. During design and operation, these factors should be taken into account, and measures such as rational flow channel design and flow velocity control should be adopted to minimize the impact of water washing and turbulence on residence time, ensuring that the separator can achieve efficient separation in a shorter residence time.
Droplet collisions within the separator are beneficial to the separation process. After collisions, droplets coalesce into larger droplets. As collisions continue, the terminal settling velocity of the droplets increases more rapidly, shortening the separation time and improving separation efficiency.
To promote droplet collisions, it is necessary to create favorable conditions while ensuring the stability of the flow field. This can be achieved by adjusting the flow velocity and increasing the disturbances within the flow channel, making the relative motion of droplets more frequent and increasing the chances of collisions. Reasonably designing the internal structure of the separator, such as installing guide plates and coalescing packing, can guide the direction of droplet movement, increase the probability of collisions, and improve separation efficiency.
To ensure the long-term efficient operation of separators, in addition to optimizing internal factors, it is also necessary to create a good external environment. This includes achieving closed transportation of oil and gas, ensuring the stable entry of recovered contaminated oil into the equipment, maintaining steady control of the liquid volume at the equipment's inlet and outlet, and conducting regular cleaning and maintenance. These external conditions are essential for the stable operation of the equipment.
Closed transportation of oil and gas can prevent contact between oil and gas and the outside air, reducing volatilization and oxidation, and maintaining stable system pressure. The stable entry of recovered contaminated oil into the equipment can avoid significant fluctuations in liquid volume that lead to unstable equipment operation. Steady control of the liquid volume at the inlet and outlet ensures that the equipment operates under designed conditions, improving separation efficiency. Regular cleaning and maintenance can promptly detect and resolve equipment issues, such as sludge accumulation and component wear, ensuring the equipment remains in good operating condition.
Separator efficiency is influenced by a wide array of interconnected factors, ranging from internal elements like particle size distribution, gas content, chemical treatment, and sludge management to structural design, residence time, and environmental conditions. Effective operation depends on understanding and optimizing these factors holistically.
Customization based on actual operational conditions is key. For example:
For crude with high gas content, focus on gas management.
For sludge-prone systems, enhance sludge removal techniques.
For underperforming units, redesign internal structures or revise chemical injection methods.
Regular monitoring and proactive maintenance are essential to ensure the separator operates within its optimal range. Only through comprehensive, integrated optimization can separator performance be maximized, supporting operational reliability and sustainable development in the petroleum industry.
Source: https://www.dfctank.com/news/how-to-improve-separator-efficiency-key-factors-practical-tips.html